Abstract
Several 8,16-Ethanoretinals 3 were synthesized from cyclohexanones. From the binding experiments of these analogs with apoprotein of phoborhodopsin, it was found that retinal was incorporated as 6s-trans conformation in the protein and the fine structure in absorption spectra of pigments were dependent on the coplanarity of the conjugated polyene structure in the chromophore. Keywords: ethanoretinal, retinal analog, phoborhodopsin, chromophore, s-trans conformation
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