Abstract
The stereocontrolled synthesis of (6 S,7 S,9 R,10 R)-6,9-epoxynadic-18-ene-7,10-diol, isolated from the brown alga, Notheia anomala, has been achieved. The key 2,3,5-trisubstituted tetrahydrofuran ring was constructed by alkylation of the sulfonyl-stabilized oxiranly anion followed by 5- endo cyclization.
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