Abstract

AbstractRegioselective access to 6‐aryl‐5‐iodobenzo[e]pyrido[1,2‐a]indoles was realized by using a facile 6‐endo‐dig iodine‐mediated cyclization under mild reaction conditions. Further functionalization of the resulting products by using Pd‐catalyzed coupling reactions was demonstrated, leading to the tetracyclic core substituted with two distinct functional groups in a regioselective fashion.

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