Abstract
2- O-Allyl-3,4-di- O-benzyl-6- O- p-nitrobenzoyl- D-glucopyranosyl chloride was condensed with 1,2-di- O-(but-2-enyl)- sn-glycerol under conditions shown previously to give predominantly α-linkages. The product was converted into crystalline 3- O-(3,4-di- O-benzyl- α- D-glucopyranosyl)-1,2-O-isopylidine- sn-glycerol, a key intermediate for the synthesis of the glucosyl diglycerides which occur in Streptococci.
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