Abstract
The dialdehydes 1 and 11 obtained by periodate oxidation of methyl α- and β- d-glucopyranoside underwent cyclization with cyanoacetamide to give 3-deoxyhexopyranosides bearing a carbamoyl and a cyano group at C-3. Three products formed from 1 and were isolated as 4, 6-benzylidene acetals and found to have the α- d- gluco, α- d- manno, and β- l- gluco configurations. From 11 was obtained a normal cyclization product having the β- d- gluco configuration, its 4-methyl ether, and a 1:2 addition product.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
