Abstract

A divergent synthesis of 6-deoxy ( 5), 4-deoxy ( 9), and 3-deoxy ( 15) derivatives of sucrose, after acetalation of sucrose with 2,2-dimethoxypropane, is detailed. Thus, 5 was prepared by hydrogenolysis of 6- S-(2-pyridyl)-6-thiosucrose, whereas 9 and 15 were obtained by radical reduction of the corresponding thiocarbonyl derivatives.

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