Abstract
Alcoxyperhalogenocyclopropanes I are easily prepared by dichlorocarbene addition to the halogenated enol ether derived from chlorotrifluoroethylene, under PTC conditions. Thermal opening of the cyclopropane ring leads to the formation of 3,3-dichloro -2-fluoroacrylic ester II by chlorine atom departure from the CFCl group in preference to the one from the CCl 2 group. This selectivity could be due to the slowing down of the substitution by the other geminal chlorine atom in the latter case. ▪
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
