Abstract

A series of ethyl 2-[(Z)-(4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene)methyl]-6-arylnicotinoates was obtained as a result of the reaction of 6-aryl-2-formylnicotinoates with rhodanine. Under alkaline conditions, they underwent recyclization to form 2-aryl-5-oxo-5H-thiopyrano[4,3-b]pyridine-7-carboxylic acids—the first representatives of new heterocyclic system.

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