Abstract
2-Alkyl- and 2-phenylazetidines are synthesized by treatment of N-(3-chloro-2,2-dimethylpropylidene)amines with alkyllithium and phenyllithium reagents, respectively. Addition of the organometallic reagent across the imino bond of the ß-chloroimine is followed by intramolecular nucleophilic substitution yielding 2-substituted azetidines.
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