Abstract
Polyaza[3.3.3]propellanes have good symmetry and strong ring tension, which are suitable as the skeleton structure of functional materials such as high energy density materials. Based on the single benzyl derivative of 3,7,9.11-tetraoxo-2,4,6,8,10-pentaaza[3.3.3]propellane (compound3), a series of 2,4,6,8,10- pentaaza[3.3.3]propellane derivatives, such as4a-cand their reduced derivatives5a-c, were synthesized successfully.
Highlights
Tricyclic propellanes are a kind of polycyclic compounds in which three ring systems share a single bond (Figure 1) [1,2,3,4,5]
Nitrocyclopropellanes, a class of heterocyclic propellanes, can be transformed to N-substituted compounds due to the high reactivity of nitrogen atoms, and they have attracted the attention of many researchers [18,19,20]
2,4,6,8,10-pentaaza[3.3.3] propellane derivatives substituted with different groups have never been reported
Summary
Tricyclic propellanes are a kind of polycyclic compounds in which three ring systems share a single bond (Figure 1) [1,2,3,4,5]. They have high reactivity and exist in many natural products [6,7,8,9,10,11,12,13]. 2,4,6,8,10-pentaaza[3.3.3] propellane derivatives substituted with different groups have never been reported. Synthesis of 2,4,6,8,10-pentaaza[3.3.3]propellane substituted with different groups
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