Abstract

AbstractAn efficient and practical method for the synthesis of (β‐trifluoromethyl‐β‐aryl)ethyl 2‐pyridyl thioethers via hydrothiolation of α‐(trifluoromethyl)styrenes with pyridine‐2(1H)‐thione was reported. The reaction proceeded smoothly and regioselectively in an anti‐Markovnikov manner with the assistance of DBU and afforded a variety of trifluoromethyl‐containing 2‐pyridyl thioethers in moderate to good yields.

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