Synthesis of 10-Methoxydiamantan-3-One

Ngo Trung Hoc,A Fokin,V Rodionov

doi:10.3390/m990

Abstract

The synthesis of diamondoids particles up to 1–5 nm, in order to detect the nanostructure in the construction of nanoelectronic devices, for which the present of quantum limitation effects are theoretically presaged, is at the present time problematic. Diamondoids have many important physical characteristics, including rigidity, lipophilicity, low strain energy, etc. Diamantane and their derivatives are also interesting for the study of nanoparticles. The present study deals with the development of the new synthetic route and diamantine-containing precursor for McMurry coupling reactions.

Highlights

Nanotechnology is currently developing new materials such as carbon-based structures
Diamondoids with the desired size larger than 1 nm, in order to explore applications in nanoelectronics [1,2,3,4], for which the present of quantum limitation effects are theoretically presaged, remains problematic at the present time. This can be solved by a coupling reaction using lower diamondoids with various spacers
Diamantane-3,10-dione was used as a starting material

Summary

Introduction

Nanotechnology is currently developing new materials such as carbon-based structures (darbon nanotubes, carbon nanofibers, fullerenes, graphene, and nanodiamonds). Ethylene ketal reaction of instead ethyleneofketal (IV) with (III), methyl in of theLiAlH 10methoxydiamantan-3-one (V), whose hydrolysis with a mixture of ethylene ketal (IV).

Results

Conclusion