Abstract

1-Organyl-1-(trimethylsiloxy)-2-(dimethylamino)ethenes were synthesized for the first time, and their reactions with trichloro(methyl)silane and trifluoro(phenyl)silane afforded silicon bis-chelates, methylbis-[2-(dimethylamino)-1-(organyl)ethenolato-N,O]siliconium chlorides and bis[1-(dimethylamino)-3,3-dimethylbut-1-en-2-olato-N,O]fluoro(phenyl)silicon(IV), respectively.

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