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https://doi.org/10.1055/s-2007-984874
Copy DOIJournal: Synlett | Publication Date: Jun 27, 2007 |
Citations: 2 |
A novel and efficient synthesis of precursors of α-amino acids is described. The key step involves a carbolithiation reaction on acyclic ene-carbamates generated from the corresponding vinylphosphates via a palladium cross-coupling reaction followed by a spontaneous internal N→C alkyloxycarbonyl migration.
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