Abstract
The preparation and 1H, 13C NMR spectra are reported for chiral 2-bromomercuri-4-dimethylaminobutane ( A), a novel useful organomercurial model having both a mercury atom attached to a chiral carbon centre and a tertiary nitrogen in the γ-position. Racemic A has been resolved partially using dibenzoyl- d tartaric acid. Redox-demercuration with a palladium(0) complex was shown to give an optically active palladium metallocycle ( B), the signs of optical rotation of A and B being the same.
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