Abstract
Two new series of tetracyanamidogermanates were prepared by solid‐state reaction of appropriate amounts of REF3 (RE = rare earth), A2[GeF6] (A = alkaline), and Li2(CN2) in evacuated silica tubes. Powder X‐ray diffraction patterns of crystalline samples of KRE[Ge(CN2)4] and CsRE[Ge(CN2)4] were indexed isotypically to KRE[Si(CN2)4] and RbRE[Ge(CN2)4], respectively. Luminescence properties of Ce3+, Eu3+, and Tb3+ doped compounds and non‐linear optical properties (NLO) of KRE[Ge(CN2)4] are reported.
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More From: Zeitschrift für anorganische und allgemeine Chemie
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