Synthesis liquid crystal composites diacrylate resin of 2-methyl-1,4-phenylene bis(4-(3-acryloyloxy)propoxy)benzoate) with methyl methacrylate

Abstract

Liquid crystal composite is a material made from monomer liquid crystal with other materials. These composites are very useful because they combine good properties of each material for many applications. Liquid crystal diacrylate resin of 2-methyl-1,4-phenylene bis(4-(3-(acryloyloxy) propoxy)benzoate) that combined with monomer methyl methacrylate (MMA) using casting solution method. Process casting solution of that material using variation weight percentage of each material. Result of casting solution was photopolymerized using preparate glass to make a thin layer polymer. Characterization thin layer polymer liquid crystal diacrylate resin with MMA using instrumentations FTIR for identify of chemical group functions molecules. FTIR spectrum showed peak at 1155 cm−1-1160 cm−1 for identifications stretching vibration of C-O-C in ester molecule and 2925-2960 cm−1 for identifying the stretching vibration of –CH3. Its band for identify bond formation between MMA with diacrylate resin. Diffractogram XRD showed thin layer polymer of PMMA-diacrylate resin has amorphous properties, because there aren’t sharp peak diffraction at 2θ 16.33°, 24.02°, 44.68°, and 72.54°. This result indicates that thin monomer methyl methacrylate blending perfect with diacrylate resin. Therefore analysis morphology of thin layer liquid crystal composite of PMMA-diacrylate resin homogen in some regions but in a little surface seen agglomeration of polymer.