Abstract
Aerobic epoxidation of isolongifolene 1 with pivalaldehyde/oxygen in perfluoro-2-butyltetrahydrofuran (FC-75) in the presence of Mn(OAc) 3·2H 2O as catalyst yielded isolongifolene-epoxide 3 in good yield. The rearrangement of isolongifolene-β-epoxide to ketone 4 was achieved.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.