Abstract
Two novel 6′-phenyl-2,2′-bipyridine ligands (L1, L2) and their CdL1,2I2 complexes (1, 2) were synthesized and characterized by elemental analysis, 1H NMR, IR, MALDI-TOF spectroscopy, and single crystal X-ray diffraction analysis. The results reveal that the central cadmium(II) atom in the complexes was coordinated by two iodide ions and two nitrogen atoms from L1, L2, forming a distorted coordination geometry. The electronic absorption properties of them were investigated on the basis of theoretical calculations (TD-DFT).
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