Abstract
Three coordination polymers have been obtained by hydrothermal synthesis, namely [Zn(imip)(H2O)2]·0.5H2O (1), [Co(imip)(H2O)2]·0.5H2O (2), and [Cd2(imip)2(H2O)3] (3) [H2imip = 5-(1H-imidazol-1-yl) isophthalic acid]. The coordination polymers were characterized by IR spectra, elemental analysis, powder X-ray diffraction, and thermogravimetric analysis. Furthermore, single-crystal X-ray analysis reveals that they have 2D structures, which are extended into 3D networks via O–H···O hydrogen-bonding interactions. The luminescent properties of these coordination polymers were investigated.
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