Abstract
The reaction of FeCl 3 · 6H 2O, potassium hydrotris(pyrazolyl)borate (KTp) and KSCN gives [FeTp 2][TpFe(NCS) 3] ( 1) and [FeTp 2] 3[Fe(NCS) 6] ( 2), respectively. The bond lengths and angles indicate that both complexes have [FeTp 2] + cations where Fe(III) ions are in typical low-spin state, and in counter ions, [TpFe(NCS) 3] − for 1 and [Fe(NCS) 6] 3− for 2 are both in high-spin state. Variable temperature magnetic susceptibility and ESR results also show that there are double spin states of iron(III) ions within the crystal lattice of both compounds.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
