Synthesis, crystal structures and magnetic properties of two three-dimensional heterotrimetallic compounds [Cu(en)2Li(H2O)][Fe(CN)6] and [Cu(en)2Li(H2O)][Co(CN)6] (en = ethylenediamine)

Wei-Wei Sima,Wen Zhang

doi:10.1016/j.inoche.2010.10.016

Synthesis, crystal structures and magnetic properties of two three-dimensional heterotrimetallic compounds [Cu(en)2Li(H2O)][Fe(CN)6] and [Cu(en)2Li(H2O)][Co(CN)6] (en = ethylenediamine)

Wei-Wei Sima, Wen Zhang

https://doi.org/10.1016/j.inoche.2010.10.016

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Journal: Inorganic Chemistry Communications	Publication Date: Oct 28, 2010
Citations: 8

Affiliation: Southeast University

#Heterotrimetallic Compounds #Three-dimensional Frameworks + Show 8 more

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Abstract

Abstract Two heterotrimetallic compounds, [Cu(en)2Li(H2O)][Fe(CN)6] and [Cu(en)2Li(H2O)][Co(CN)6] (en = ethylenediamine), were synthesized and characterized. They are isostructural and crystallize in the orthorhombic space group Pbca at 293 K. The structures of the two compounds are composed of one-dimensional zigzag Fe/Co–C≡N–Cu chains linked by Li(I) ions into three-dimensional frameworks. Magnetic study of [Cu(en)2Li(H2O)][Fe(CN)6] reveals a weak magnetic interaction in the compound.

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