Abstract
A new nickel (II) complex [NiL2](H2O)4(SO4), where L = 1,4-diazepane, has been synthesized by interaction between nickel sulfate and 1,4-diazepane. This complex crystallizes in the Pmcn orthorhombic unit cell with parameters a = 9.173(2) Å, b = 11.691(2) Å, c = 17.015(2) Å, V = 1824.9(5) Å3, and Z = 4. It possesses a mononuclear structure in which the central NiII atom is coordinated by four N atoms from two 1,4-diazepane ligands in a distorted square-planar geometry. In the crystal, the anions [SO4]2−, the cations [NiL2]2+, and the water molecules are held together by H-bonding to form a 2D supramolecular structure. Differential scanning calorimetry (DSC) results showed that this compound undergoes a reversible order–disorder phase transition at 486 K with a hysteresis of 32 K. In addition, electrical conductivity measurements showed that the complex has a conductivity value of 4.15 10−4 Ω−1cm−1 at 390 K. The Density Functional Theory (DFT) study results qualitatively supported the experimental data obtained by X-ray diffraction and thermogravimetric analysis (TGA).
Published Version
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