Abstract
A new asymmetrical substituted triazole, 3-phenoxymethyl-4-phenyl-5-(2-pyridyl)-1,2,4-triazole (L) and its complexes, cis-[Cu2 L 2Cl4]·2CH3CN (1) and trans-[CoL 2Cl2]·2H2O·2CH3CN (2), have been synthesized and characterized by IR, single-crystal X-ray diffraction, thermogravimetric analyses and Hirshfeld surfaces. In the structure, two L are mainly stabilized by an intermolecular C–H⋯N hydrogen bond. In 1 (or 2), each L involves a doubly-bidentate (or chelating bidentate) coordination mode through one pyridine and two nitrogens (or one) of triazole, respectively. Complex 1 has a distorted trigonal bipyramidal [CuN3Cl2] core with two cis Cl− while 2 shows a distorted octahedron [CoN4Cl2] with two trans Cl−. We also prepared molecular Hirshfeld surface and fingerprint plot for L, 1 and 2, which revealed the influence of different metals on coordinate of L.
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