Abstract
The binuclear silver(I) complex [Ag2(η2-SPPh3)2(SPPh3)2](BF4)2 has been synthesized. Crystal analysis shows the coordination sphere around Ag(I) can be described as a three-coordinated slightly distorted planar triangular configuration with both monodentate and monoatomic bidentate bridging coordination modes for the SPPh3 ligand. The fluorescence properties of free SPPh3 and the Ag(I) complex have been studied in the solid state. The Ag(I) complex shows quasi-reversible Ag+/Ag pairs in its electrochemistry and has significant antioxidant activity against hydroxyl radicals.
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