Abstract
A complex of palladium(II) chloride with tris(2-pyridylmethyl)amine (TPA) has been synthesized and characterized. The single-crystal structure has been determined by X-ray diffraction analysis. The palladium(II) atom in the title complex is in a square planar environment surrounded by three nitrogen atoms of TPA and one chlorine atom, with bond lengths in the range of 2.004–2.012 Å for PdN and 2.296 Å for PdCl. The properties of [Pd((TPA)Cll)]·ClO 4 have been further studied with IR and UV-vis techniques. IR spectra show that most of the bands of [Pd((TPA)Cl)]·ClO 4 are shifted to lower wavenumbers in comparison with those of the TPA ligand.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
