Abstract
An attempted isolation of the elusive diammonium tetraoxidotungstate (NH4)2[WO4] as its imidazole (Im) adduct resulted in the serendipitous formation of hepta(ammonium) penta(1H-imidazol-3-ium) paratungstate B tetrahydrate having formula [NH4]7[ImH]5[W12O42]·4H2O (1). The synthesis, vibrational spectra, crystal structure and thermal study of the mixed cationic paratungstate tetrahydrate 1 are reported. The structure of 1 consists of a centrosymmetric paratungstate [W12O42]12– anion devoid of internal hydrogen atoms, which is charge balanced by ammonium and 1H-imidazol-3-ium cations. One of the four unique NH4 + cations and one of the three crystallographically independent 1H-imidazol-3-ium cations are disordered around a center of inversion. The cations, [W12O42]12– anion and the unique lattice water molecules are joined with the aid of five varieties of hydrogen bonding interactions. A comparative study of twenty-three partaungstates is described. Thermal decomposition of 1 results in the formation of monoclinic tungsten trioxide WO3.
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