Abstract
Abstract A supramolecular compound Na3(HABOB)(H2ABOB)[MnMo9O32]·5.5H2O (ABOB = moroxydine) has been synthesized and characterized by elemental analyses, IR spectrum, diffuse reflectance spectrum, room temperature magnetic moment, single crystal X-ray diffraction, and TG analysis. It exhibits a two-dimensional, layered inorganic framework constructed from Waugh-type polyanions [MnMo9O32]6− and Na+ ions linkers. Protonated ABOB molecules are hydrogen-bonded to the left- and right- handed [MnMo9O32]6− enantiomorphs to construct two kinds of infinite organic–inorganic hybrid chains.
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