Abstract
AbstractA new type heterobimetallic complex containing lanthanide and transition metal carbonyl cluster (LnM carbonyl cluster), Sm2{OOCCCo3(CO)9}2{OOCCF3}4{(CO)9Co3CCOOH}4, has been synthesized by reaction of (CO)9Co3CCOOH with Sm(OOCCF3)3(H2O)2, and structurally characterized by single‐crystal X‐ray diffraction. Application of the complex as a catalyst precursor for hydrogenation of carbon monoxide (Fischer–Tropsch reaction) was explored, and the thermogravimetric behavior and magnetic properties of the compound were examined as well. Copyright © 2008 John Wiley & Sons, Ltd.
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