Synthesis, Crystal Structure, and Photoluminescent Properties of a Series of LnIII–CuI Heterometallic Coordination Polymers Based on Cu4I3 Clusters and Ln–ina Rod Units

Abstract

A novel series of LnIII–CuI heterometallic coordination polymers (HCPs) {[Ln2Cu4I3(ina)7(DMA)2]n·nDMA, Ln = La (1), Ce (2), Pr (3) Nd (4), Sm (5), Eu (6), Gd (7), Tb (8), Dy (9) Ho (10), Er (11), Yb (12), Hina = isonicotinic acid, DMA = N,N-dimethylacetamide} were synthesised by a solvothermal reaction. The structures of compounds 1–12 were characterised by elemental analysis, FT-IR spectroscopy, thermogravimetric analysis, and powder X-ray diffraction. Single crystal X-ray diffraction studies revealed that 1–12 are isomorphous and are 3D heterometallic coordination polymers based on inorganic Cu4I3 clusters and Ln2(ina)7(DMA) rod units. In addition, the luminescent properties of compounds 5–9 have been investigated in detail. All of them exhibited green light emission due to the synergistic effects of characteristic emissions of lanthanide ions and iodide-to-copper charge transfer.