Abstract
A new 1-D MnII chain, [Mn(μ 1,3-N3)(phenCl)2]n (ClO4)n (phenCl = 2-chloro-1,10-phenanthroline), was synthesized with single μ 1,3-azido as bridge and 2-chloro-1,10-phenanthroline as coligand, and its crystal structure determined by X-ray crystallography. In the complex, MnII is located in a distorted octahedral geometry, and azide is an end-end bridge, linking two MnII ions with separation of 5.7356(10) Å, forming a 1-D chain. In the crystal, there are two kinds of π-π stacking between adjacent chains. The fitting of the variable-temperature (2.00–320 K) magnetic susceptibilities gave an anti-ferromagnetic interaction of J = –5.99 cm–1 (), among the stronger magnetic interaction in MnII complexes with azido as single end-end bridge. Reported experimental results do not confirm clearly the magneto-structural correlations revealed by theoretical calculations.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
