Abstract
A one-dimensional coordination polymer [Co(μ 1,3-NCS)2(npdo)2] n (npdo = 4-nitropyridine N-oxide) has been synthesized and structurally determined by X-ray crystallography. The complex crystallizes in the orthorhombic space group of Pbcn with a = 22.688(5) Å, b = 7.2636(17) Å, c = 10.299(2) Å. Adjacent Co(II) ions are coordinated by two μ 1,3-SCN− bridging ligands, forming a one-dimensional chain along the c axis and the npdo coordinates to Co(II) ion as a terminal ligand. The thermal variation of the magnetic moments of the complex reflects the antiferromagnetic interaction between the bridged Co(II) ions above 20 K and the ferromagnetic transition or the strong short-range spin interaction below 20 K.
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