Abstract
A one-dimensional polynuclear copper(II) complex [Cu(μ1,6-dmpzdo)(SCN)2] n (where dmpzdo = 2,5-dimethylpyrazine-1,4-dioxide) has been synthesized and its crystal structure determined by X-ray crystallography. The coordination geometry of Cu(II) atom is a square plane and each Cu(II) ion is connected by two μ1,6-dmpzdo bridging ligands, leading to the formation of a one-dimensional chain. ESR spectra indicate magnetic coupling between the bridged Cu(II) ions. The fitting of the variable-temperature magnetic susceptibility data (4–300 K) gave 2J = −68.69 cm−1.
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