Abstract
A new oxamido-bridged trinuclear copper(II) complex [(CuL)2Cu](ClO4)2·0.5H2O (L = the dianion of 2,3-dioxo-5,6,14,15-dibenzo-7,13-bis(ethoxycarbonyl)-1,4,8,12-tetraazacyclotetradeca-7,12-diene) has been synthesized by self-assembly and characterized. X-ray diffraction analysis reveals that the title complex is monoclinic, space group P21, with a = 16.213(5), b = 9.811(3), c = 18.802(6) Å, β = 96.790(5)°. The central copper(II) ion lies in a distorted octahedral environment. Terminal coppers have square pyramidal coordination geometry. Magnetic measurements show there is strong antiferromagnetic interaction between the central and the terminal Cu(II) ions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.