Synthesis, Crystal Structure and Luminescent Property of Cd (II) Complex with N-Benzenesulphonyl-L-leucine

Xishi Tai,Jinhe Jiang

doi:10.3390/ma5091626

Abstract

A new trinuclear Cd (II) complex [Cd3(L)6(2,2-bipyridine)3] [L = N-phenylsulfonyl-L-leucinato] has been synthesized and characterized by elemental analysis, IR and X-ray single crystal diffraction analysis. The results show that the complex belongs to the orthorhombic, space group P212121 with a = 16.877(3) Å, b = 22.875(5) Å, c = 29.495(6) Å, α = β = γ = 90°, V = 11387(4) Å3, Z = 4, Dc= 1.416 μg·m−3, μ = 0.737 mm−1, F (000) = 4992, and final R1 = 0.0390, ωR2 = 0.0989. The complex comprises two seven-coordinated Cd (II) atoms, with a N2O5 distorted pengonal bipyramidal coordination environment and a six-coordinated Cd (II) atom, with a N2O4 distorted octahedral coordination environment. The molecules form one dimensional chain structure by the interaction of bridged carboxylato groups, hydrogen bonds and π-π interaction of 2,2-bipyridine. The luminescent properties of the Cd (II) complex and N-Benzenesulphonyl-L-leucine in solid and in CH3OH solution also have been investigated.

Highlights

Investigation of the inorganic-organic hybrid materials with carboxylate ligands has gained considerable attention during the last decade due to their attractive structures and promising potential applications for catalysis, gas storage, magnetic, luminescence materials [1,2,3,4,5,6,7]
Materials 2012, 5 shown that the organic ligands containing multi-oxygen and nitrogen atoms can coordinate with metal ions in different ways, resulting in the formation of various metal-organic frameworks with specific topologies and useful properties
We have been exploring the preparation of inorganic-organic hybrid materials by combining metal ions and organic ligands containing multi-oxygen and nitrogen atoms

Summary

Introduction

Investigation of the inorganic-organic hybrid materials with carboxylate ligands has gained considerable attention during the last decade due to their attractive structures and promising potential applications for catalysis, gas storage, magnetic, luminescence materials [1,2,3,4,5,6,7]. Materials 2012, 5 shown that the organic ligands containing multi-oxygen and nitrogen atoms can coordinate with metal ions in different ways, resulting in the formation of various metal-organic frameworks with specific topologies and useful properties. The Cd (II) complexes have gained considerable attention due to their luminescent properties [4]. We have been exploring the preparation of inorganic-organic hybrid materials by combining metal ions and organic ligands containing multi-oxygen and nitrogen atoms. The luminescent properties of the Cd (II) complex and N-Benzenesulphonyl-L-leucine in solid and in CH3OH solution have been investigated

Methods

Results

Conclusion