Abstract
A new cadmium coordination polymer based on imidazole-4,5-dicarboxylic acid (H3IDC) and 4,4′-bipyridine (Bipy), {[Cd9(IDC)2(HIDC)6(Bipy)4] · 2N(CH3)(CH2CH3)2 · 2DMF} n , has been synthesized under solvothermal conditions and characterized by energy dispersive X-ray spectroscopy, elemental analysis, FT-IR spectroscopy, thermal analysis, and single crystal X-ray diffraction. It crystallizes in the orthorhombic system, space group Pnnm with a = 20.530(2) Å, b = 15.5957(14) Å, c = 16.3846(15) Å, α = β = γ = 90°, V = 5245.9(9) Å3, and Z = 2. The complex exhibits a 3-D structure with channels along the c-axis, in which the free N,N-dimethylformamide and methyl-diethyl-amine molecules are located. The thermal behavior and luminescence of this complex have also been studied in the solid state.
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