Abstract
A novel organic–inorganic complex, [Ce(NMP)3(H2O)6][Ce(NMP)3(H2O)5][P2Mo18O62]·0.5 NMP·H2O, (NMP = N-methyl-2-pyrrolidone) consisting of [Ce(NMP)3(H2O)6]3+, [Ce(NMP)3(H2O)5]3+ and [P2Mo18O62]6− entities, has been synthesized and characterized by element analysis, i.r. spectra, and single crystal X-ray structural analysis. The results of the single crystal X-ray diffraction analyses and i.r. spectra are agreement; both show that there is interaction between the metal cation units and the Dawson cluster. The low temperature e.s.r. spectrum indicates thermal electron delocalization occurs among the Mo atoms in the compound.
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