Synthesis, Crystal Structure, and Characterization of A New Hydrogen Phosphate Templated By 3-Aminophenyl Sulfone

Abstract

The synthesis and crystal structure of a new noncentosymmetric compound with the general formula: [C48H51N8O8S4](HPO4)H2PO4 are reported. The structure, determined by single-crystal X-ray diffraction at 150 K can be described as organic layers [C48H51N8O8S4]3+ parallel to the (a and c) plane between which the inorganic groups consisting of H2PO4 − and HPO4 2− entities are inserted as inorganic layers. In this atomic arrangement, H-bonds and Vander-Waals interactions between the different species play an important role in the tridimensional network cohesion. Solid-state 13C and 31P MAS NMR spectroscopies are in agreement with the X-ray structure. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.