Abstract
AbstractA one‐dimensional (1D) Ni(II) coordination polymer, {[Ni(oba)(1,3‐bix)(H2O)]⋅H2O}n (1), where H2oba=4,4′‐oxybis(benzoic acid) and 1,3‐bis(imidazol‐l‐yl‐methyl)benzene=1,3‐bix, was hydrothermally synthesized and characterized through IR spectroscopy, elemental and thermal analysis, single‐crystal X‐ray diffraction, and Hirshfeld surface analyses. X‐ray diffraction structural analysis has revealed that the oba and 1,3‐bix ligands connects the Ni(II) atoms to form a square‐wave 1D chain, which is further extended into 2D supramolecular layers through O−H⋅⋅⋅O hydrogen bonds and π⋅⋅⋅π stacking interactions. 1 shows intense luminescence in H2O and exhibits a selectivity and detection for Fe3+ ions through the fluorescence quenching effect at room temperature.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
