Synthesis, characterization of poly-2- (2-hydroxybenzylideneamino)-6-phenyl-4,5,6, 7-tetrahydrobenzo[b ]thiophene-3-carbonitrile: Investigation of antibacterial activity and optical properties

Abstract

The oxidative polycondensation reaction conditions of 2-(2-hydroxybenzylideneamino)-6-phenyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile were examined. The magnitude of the reflectance of the polymer decreases sharply with increasing of wavelength up to 524 nm, then reflectance of the polymer increases slowly with increasing of wavelength. The refractive index values of the polymer vary from 1.474 to 2.350. The Ep and Ed values of the polymer were found to be 4.56 and 7.068 eV, respectively. Absorption coefficient K of the polymer is of the order 817.062–1434.77 m−1. Angle values of incidence and refraction of the polymer vary from 57.36 to 66.95° and from 23.05 to 32.65°, respectively. The film-phase thickness of the polymer increases with increasing photon energy. The thickness, d, of the polymer was of the order 439.3–4184.7 Å for 190 and 1100 nm, respectively. The real part of dielectric constant of the polymer decreases slowly with increasing of frequency up to about 600 THz, then the real part of dielectric constant of the polymer increases sharply with increasing of frequency. The real and imaginary parts of dielectric constant of the polymer vary from 2.17 to 5.52 and from 5.81 × 10−5 to 3.58 × 10−4, respectively. Finally, polymer was tested for antibacterial activities against some bacteria. POLYM. ENG. SCI., 2012. © 2012 Society of Plastics Engineers