Abstract

We have prepared polycrystalline, single-phase Nd 1− x Sr x CoO 3 materials (0≤ x≤0.40) using the nitrate decomposition method and we have studied how their structural, magnetic and transport properties change upon Sr 2+ doping. In this context we find that these series of compounds crystallize in GdFeO 3-type perovskite structures whose cell volume increases as x gets higher. From the magnetic point of view, this doping makes the materials evolve towards a ferromagnetic behavior as x increases, so that for x>0.20 the samples are already ferromagnetic below a T c∼225 K. Also, their electrical conductivity progressively increases with x. Nevertheless the materials remain semiconducting for x≤0.30 and only the sample with x=0.40 displays a M–I transition as a function of temperature ( T MI∼160 K).

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