Abstract

In this paper, we present a new dinuclear triazenido‑copper(I) complex, [Cu2(L)2] 1, formed by the reaction of the triazenido ligand, 1,3-bis[(2-bromo)benzene]triazene (HL) with CuCl. At room temperature, this copper complex shows photoluminescence at 667nm. Additionally, electrochemical investigations reveal that the electrocatalytic systems based on this copper complex can afford 91.23 and 582.2mol of hydrogen per mole of catalyst per hour (mol H2/mol catalyst/h) from acetic acid at an overpotential (OP) of 991.6mV and an aqueous buffer at an OP of 837.6mV, respectively. The findings show that transition metal complexes may exhibit various functions in different directions.

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