Synthesis, Characterization, Crystal Structures, and Biological Activity of Nickel(II), Manganese(II) and Cadmium(II) Complexes Derived from 4-Bromo-N'-(1-(Pyridin-2-YL)ethylidene)benzohydrazide

Abstract

Three nickel(II), manganese(II) and cadmium(II) complexes, [NiL2] (I), [MnL2] (II) and [Cd(HL)2(NO3)]·NO3 (III), derived from 4-bromo-N'-(1-(pyridin-2-yl)ethylidene)benzohydrazide (HL) were prepared and characterized by IR and UV spectra. Structures of the complexes were further confirmed by single crystal X-ray diffraction techniques (CIF files CCDC nos. 1874307 (I), 1874308 (II), and 1874309 (III)). The Ni atom in complex I and the Mn atom in complex II are in octahedral coordination. The Cd atom in complex III is in square antiprism coordination. The nickel complex is effective on the inhibition of Jack bean urease.