Abstract
Four new bis(dialkyldithiocarbamates) of zinc, [Zn(S 2CNMeR) 2] 2 (where R = Et, Pr n, Pr i and Bu n : compounds 1, 2, 3 and 4 have been synthesized and characterized by X-ray crystallography, spectroscopic methods and differential scanning calorimetry X-ray crystallographic characterization indicated centrosymmetric dimeric structures for 1–4. The central region of each molecule, consisting of three edge-sharing four-membered rings, is structurally similar to the symmetric bis(dialkyldithiocarbamates) [Zn(S 2CNEt 2) 2] 2 and [Zn(S 2CNPr 2 i) 2] 2, characterized in earlier studies. Preliminary results on chemical vapour deposition of polycrystalline ZnS films from 4, which is considerably more volatile than the previously used precursor [Zn(S 2CNEt 2) 2] 2, are reported.
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