Abstract
AbstractTwo new 4d‐4f coordination polymers, [Ag2Nd(nic)4(H2O)4·(ClO4)·H2O] (1) and [Ag8Yb4(inic)8(ox)6]· [Ag2(inic)2] (2) [nic = nicotinate, inic = isonicotinate and ox = oxalate] have been synthesized and characterized by element analysis, IR spectroscopy and thermal analysis, as well as single crystal X‐ray diffraction. Complex 1 exhibits a wavelike layer that is assembled from neodymium‐carboxylate subunits, silver centres and perchlorate ions. Complex 2 represents a extended heterometallic sandwich‐like layered network that is constructed from ytterbium‐oxalate layers and Ag(inic) chains.
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