Synthesis, characterization, and thermal aging behavior of HCl‐doped polyaniline/TRGO nanocomposites

Abstract

ABSTRACTIn this article polyaniline (PANI) nanocomposites containing thermally reduced graphene oxide (TRGO) were synthesized and characterized before and after thermal aging. The nanocomposites were prepared through in situ oxidative polymerization of aniline in the presence of TRGO nanoplatelets. FTIR and Raman spectroscopies, XRD, FESEM, and electrical conductivity measurements were used to characterize synthesized materials. PANI/TRGO nanocomposites showed considerably higher electrical conductivity when compared to pure PANI, which was associated with the higher electrical conductivity of TRGO and increased crystallinity of PANI in the presence of TRGO. Pure PANI and PANI/TRGO nanocomposites were thermally aged at 70, 80, 90, and 100 °C. The results showed that the characteristic time of thermal aging process is higher for PANI/TRGO nanocomposites and increases with TRGO loading, which indicates better stability of conductivity during thermal aging process. On the other hand, the characteristic time of thermal aging reduced with aging temperature and a fast decrease was observed from 80 to 90 °C. Improved resistance over thermal aging can be attributed to the barrier effect of TRGO nanoplatelets to the dopant molecules, which retards conductivity degradation in the thermal aging process. Furthermore, TRGO increases PANI crystallinity and it can also prevent crystallinity reduction during thermal aging process. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44635.