Abstract
Four diorganotin(IV) complexes, bis[(trimethylsilyl)methyl]tin salicylaldehyde thiosemicarbazonate monohydrate(1), bis[(trimethylsilyl)methyl]tin 3-methoxysalicylaldehyde thiosemicarbazonate (2), bis[(trimethylsilyl)methyl]tin 5-tert-butyl-3-methylsalicylaldehyde thiosemicarbazonate (3), and bis[(trimethylsilyl)methyl]tin 2-oxylnaphthaldehyde thiosemicarbazonate (4) have been synthesized by reactions of (Me3SiCH2)2SnCl2 with the corresponding semicarbazone. The four complexes were characterized by IR and NMR spectroscopy and elemental analyses. The X-ray studies of compounds 1 and 4 showed that the thiosemicarbazone ligands act as tridentate ligands chelating to the central tin atoms, and thus the tin atoms were five coordinated in trigonal bipyramidal geometry for both compounds. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Phosphorus, Sulfur, and Silicon and the Related Elements
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
