Abstract
Reactions of chlorotrimethylsilane with sodium salts of 2-aminocyclopentene-1-carbodithioic acid and its N-/S-alkyl derivatives, having the general formula and in 1 : 1 molar ratio in refluxing benzene solution lead to the formation of triorganosilicon(IV) derivatives, and , respectively. Characterization of these complexes by elemental analysis, molecular weight measurements, and IR, NMR (1H, 13C and 29Si) spectral analysis reveals a four coordination around the silicon atom in trimethylsilicon(IV) derivatives of 2N-alkylaminocyclopentene-1-carbodithioic acid and five coordination in the S-alkyl 2-aminocyclopentene-1-carbodithioic acid derivative.
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