Abstract
Octakis(p-fluorophenoxy)-substituted phthalocyanine and its complexes of gallium and indium have been obtained in high yields (89% and 86% respectively). Unmetallated phthalocyanine and gallium complex were synthesized for the first time and the new method for the synthesis of indium complex was proposed. The obtained compounds were characterized by a combination of MALDI-TOF mass spectrometry, UV–Vis, and NMR spectroscopies. Photochemical properties of gallium and indium phthalocyanines were investigated. It was shown that these complexes maintained high production of singlet oxygen and potentially can be used in photodynamic therapy.
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