Abstract

In the coordination sphere of β-diketiminato nickel(II) moieties hydrazine can be reversibly deprotonated, once to yield a hydrazido(–1) complex (which decomposes to an ammine complex at elevated temperatures) and twice to give a Ni(N2H2) complex with an electronic structure intermediate between nickel(II) hydrazido(–2) and nickel(0) diazene.

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